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Bismuth Vanadate (BiVO4) PLD Target

Bismuth Vanadate (BiVO4) PLD Target

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Material Bismuth Vanadate 
Formula BiVO4
Purity 99.9%
Typical Substrates

Bismuth Iron Oxide, Bismuth Ferrite, Vanadium Dioxide

Crystal Structure Tatragonal 

 

Bismuth Vanadate Thin Film Targets for Pulsed Laser Deposition

Introduction to Bismuth Vanadate Thin Film

Bismuth vanadate (BiVO4) thin film is a type of material that has received significant attention due to its potential use in photoelectrochemical (PEC) water splitting for renewable energy production, solar energy conversion, and catalysis. Thin film deposition techniques, such as chemical vapor deposition (CVD), pulsed laser deposition (PLD), and sputtering, have been widely used to fabricate BiVO4 thin films with precise control over their thickness and microstructure.

Bismuth vanadate is a semiconductor with a narrow bandgap of about 2.4 eV, which allows it to efficiently absorb visible light. When exposed to sunlight, the electrons in the material become excited and can be used to generate an electrical current, which is the basis of PEC water splitting.

 It is a light absorber and efficient photocatalyst for water splitting, making it useful for various applications such as solar energy conversion, environmental remediation, and electrochromic devices.

Typical substrates with a good lattice match are used for the epitaxial growth of Bismuth Vanadate

The epitaxial growth of BiVO4 typically requires the use of substrates with a good lattice match to minimize lattice mismatch-induced defects and strain. Some of the typical substrates used for the epitaxial growth of BiVO4 are:

  1. Yttrium-stabilized zirconia (YSZ) substrate
  2. Strontium titanate (SrTiO3) substrate
  3. LaAlO3 substrate

Comparison to Similar Materials

BiVO4 is often compared to other metal oxides such as titanium dioxide (TiO2) and zinc oxide (ZnO) due to its similar properties as a photocatalyst. However, BiVO4 has a narrower bandgap compared to TiO2 and ZnO, which makes it more efficient in absorbing visible light. BiVO4 also has a higher charge carrier mobility and a longer electron-hole lifetime, which makes it a more efficient photocatalyst.

Crystal Structure of Bismuth Vanadate Thin Film

BiVO4 has a tetragonal crystal structure and belongs to the scheelite family of compounds. It has a space group of I41/amd and lattice parameters of a=b=5.451 Å and c=12.995 Å.

List of 5 Similar Thin Film Materials to Bismuth Vanadate

  • Bismuth Iron Oxide
  • Bismuth Ferrite
  • Vanadium Dioxide
  • Bismuth Titanate
  • Bismuth Cobalt Zinc Oxide

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